Geochemistry

Chromium Geochemistry: Eh-pH diagram-Toxicity-Stability Diagrams

August 16th, 2010  |  by  |  published in Geochemistry | Leave A Comment »

Chromium 0.1 ppm with 150 ppm HCO3-SO4-- Brezinaite Formation

Chromium is highly insoluble in water. Chromium can only be in solution at a very low pH below 3.5. In this exercise we will generate Eh-pH diagrams to study stable and  soluble phases. Cr(VI) is much more toxic and mobile than Cr(III). So, speciation of chromium is very important. Hexavalent chromium exists in alkaline, strongly [...]

Manganese Geochemistry: Eh-pH diagram-stability fields in Natural Water

August 16th, 2010  |  by  |  published in Geochemistry | Leave A Comment »

Case 1 Type 2: Manganese Solubility

In this article we are going to investigate the Manganese solubility in natural water with the help of various Eh-pH diagrams. We will also investigate the effect of bicarbonate (alkalinity) and sulfate on Manganese solubility. At the end we will compare the solubility of manganese against iron solubility. Background: In natural surface and groundwater, manganese [...]

Alabandite (MnS) Geochemistry:Eh-pH diagram-Solubility-Stability Field

August 13th, 2010  |  by  |  published in Geochemistry | Leave A Comment »

Eh-pH with Alabandite activity 1 in presence of free so4 at 300 C

Alabandite is a sulfide mineral often found in epithermal sulfide vein deposits. The name of the mineral is derived from its supposed discovery locality at Alabanda, Aïdin, Turkey. Chemical Formula:     MnS Composition:     Molecular Weight = 87.00 gm General physical properties and color photograph of Alabandite can be found at http://www.mindat.org/min-89.html Google Image also [...]

Composition of sea water: speciation model using Geochemist’s Workbench

August 10th, 2010  |  by  |  published in Geochemistry | 1 Comment »

Stiff Diagram of SpecE8 model of sea water

It is wonderful what you can really do with Geochemist’s workbench. In this exercise, I am going to use the known concentrations of sea water and use Geochemist’s workbech to perform a little exercise. Geochemist workbench has different modules. In this particular exercise, I am going to use the SpecE8 module. This module is similar [...]

PHREEQC: Molality and mole calculations

July 28th, 2010  |  by  |  published in Geochemistry | Leave A Comment »

If you hate doing mole calculations by hand, check out this PHREEQC tip. Good thing about the free software by USGS is that you can input the variables as mg/L (or other units) and it will first speciate the solutions to give you the molality and moles for each component. Lets just use one example [...]

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